Large Magnetocaloric Effect in a Wells-Dawson Type {Ni6Gd6P6} Cage

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Large magnetocaloric effect in a Wells-Dawson type {Ni6Gd6P6} cage.

Magnetic refrigeration is based on the magnetocaloric effect (MCE) which relies on the entropy change of a material when placed in a magnetic field.1 Molecular magnets have recently been examined in this context, especially high spin isotropic magnetic molecules.2-8 The very large MCE observed for some of these cages suggests they could be used as a replacement for helium-3 in some applications...

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Adiabatic demagnetization is currently gaining strong interest in searching for alternatives to (3)He-based refrigeration techniques for achieving temperatures below 2 K. The main reasons for that are the recent shortage and high price of the rare helium isotope (3)He. Here we report the discovery of a large magnetocaloric effect in the intermetallic compound YbPt2Sn, which allows adiabatic dem...

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ژورنال

عنوان ژورنال: Angewandte Chemie International Edition

سال: 2011

ISSN: 1433-7851

DOI: 10.1002/anie.201008074